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Automatic Potentiometric Titrator for Acid Value and Peroxide Value

Automatic Potentiometric Titrator for Acid Value and Peroxide Value

【Introduction】Uses cold-solvent automatic potentiometric titration for acid value and potentiometric titration for peroxide value, with national-standard programs for both pre-installed. The burette is driven by a closed-loop stepper motor with a minimum dispensing volume of 0.1 µL, and automatic multi-jump endpoint recognition keeps routine testing consistent, with a general titration mode for other determinations.

Product model:

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Product details

Acid peroxide value detector on a laboratory bench with glassware and a flask of oil

Nine feature icons including Android system, 7-inch touch screen and high precision titration system

Scope of application showing edible oils and fats, oil containing food and other oil and fat products

Detection principle of acid value and peroxide value with non-aqueous pH and redox electrodes

High precision titration system with closed loop stepper motor drive and 0.1 microlitre minimum addition

National standard one click titration with automatic endpoint recognition and curve drawing

Complete data integrity with third level user permission management and audit tracking

Intelligent interaction with Android 10 system and 7-inch color capacitive touch screen

Cloud based remote software upgrade and WiFi detection data upload to a client

National standard testing methods GB 5009.229-2025, GB 5009.227-2023 and JJG 814-2015

Other functions including dual electrode configuration, thermal printer, local storage and data interfaces

Technical parameter table of the automatic potentiometric titrator

Configuration list of standard accessories including burettes, electrodes, titration cups and tubing

Shandong Hengmei Electronic Technology Co., Ltd. team photo

Company laboratories and business scope across food, agriculture and environmental testing

Product Overview

Acid value and peroxide value are routine indicators of how far an oil or fat has oxidised, and both are measured here on a single automatic potentiometric titrator. HM-DAP is designed for the precise determination of acid value and peroxide value in food: acid value is measured by cold-solvent automatic potentiometric titration and peroxide value by potentiometric titration, with national-standard programs for both already installed. Automatic endpoint recognition supports one-click testing, and a general titration mode remains available for other potentiometric titrations.

Typical users are food producers monitoring frying oil and finished goods, quality inspection agencies, and research institutes studying the oxidative stability of oils and fats. The instrument is operated from an Android 10 interface with a 7-inch colour touch screen and stores results locally with an audit trail.

Key Features

  • Two national-standard determinations in one instrument: acid value and peroxide value, each with a pre-installed program.
  • One-click testing with automatic endpoint determination (multiple jump recognition), automatic curve plotting, and automatic calculation and reporting.
  • High-precision titration system with a closed-loop stepper motor, resolution ≥ 1/1,500,000 (reliable resolution ≥ 1/300,000) and a minimum dispensing volume of 0.1 µL.
  • Standard non-aqueous composite pH electrode for acid value and redox electrode for peroxide value, with multiple professional electrodes available optionally for other determinations.
  • Creation, editing, storage and quick recall of detection methods, so routine procedures can be repeated consistently.
  • Three-level user permission management and a complete audit trail, consistent with laboratory quality management standards such as GLP/GMP.
  • Large-capacity local storage for detection data and titration curves, plus a built-in thermal printer for immediate results.
  • Cloud connection for remote software upgrades and Wi-Fi upload of data with client login management.

Applications

The instrument is used to monitor acid value or peroxide value across the following sample groups.

Edible oils and fats

  • Animal and vegetable oils, hydrogenated oils, shortening, margarine, vegetable fat cream and powdered oils.

Oil-containing foods

  • Fried, puffed and baked processed foods, nuts and seasoning sauces.

Other oil and fat products

  • Oil-containing raw materials and finished products that require acid value or peroxide value monitoring.

Method conditions for the two determinations are as follows. Acid value (cold-solvent automatic potentiometric titration): the oil is dissolved in isopropanol and anhydrous ether (1:1), free fatty acids are neutralised with potassium hydroxide standard solution, and the endpoint is determined from the pH jump measured by a non-aqueous phase pH electrode. Peroxide value (potentiometric titration): the oil is dissolved in isooctane and glacial acetic acid (2:3), peroxides react with potassium iodide to form iodine, and the solution is titrated with sodium thiosulfate standard solution, with the endpoint determined from the potential jump.

Technical Specifications

Method and Compliance

ParameterSpecification
Measurement methodAutomatic potentiometric titration (compliant with GB 5009.229-2025 and GB 5009.227-2023)
Acid value repeatabilityComplies with the national standard requirement: acid value ≤ 1 mg/g, absolute difference between two independent determinations ≤ 15%; acid value > 1 mg/g, ≤ 12%
Peroxide value repeatabilityComplies with the national standard requirement: absolute difference between two independent determinations ≤ 10%
Instrument titration repeatability≤ 0.2% (RSD)

Titration and Measurement Performance

ParameterSpecification
Burette driverHigh-precision closed-loop stepper motor; resolution ≥ 1/1,500,000 (theoretical conversion), reliable resolution ≥ 1/300,000
Minimum dispensing volumeSoftware-configurable, down to 0.0001 mL (0.1 µL)
Burette capacity tolerance10 mL burette: ± 25 µL; 20 mL burette: ± 35 µL
Potential measurement−2,000 to +2,000 mV; resolution 0.1 mV; meter indication error ± 0.03% FS
pH measurement−20.000 to +20.000 pH; resolution 0.001 pH; basic error ± 0.003 pH (electronic unit display range, converted from ± 2,000 mV by the Nernst equation)
Temperature measurement−5 to 105 °C; resolution 0.1 °C; basic error ± 0.2 °C

System and Operation

ParameterSpecification
Operating systemAndroid 10
Display7-inch capacitive touch screen
Data storage≥ 100,000 records
Data interfacesUSB, Wi-Fi, Ethernet
PrinterBuilt-in thermal printer

Power, Environment and Physical Specifications

ParameterSpecification
Power supplyAC 110–240 V, 50–60 Hz
Operating environmentTemperature 0–40 °C, humidity 10%–75% RH
Storage environmentTemperature 0–40 °C, humidity 10%–90% RH
Dimensions310 mm × 226 mm × 233 mm
Main unit weightApprox. 3.7 kg

Configuration / Accessories

Standard configuration (supplied with the instrument):

ItemQtySpecification
Instrument mainframe1—
Non-aqueous titration composite electrode16510 glass pH non-aqueous titration composite electrode
Redox electrode15004 redox electrode
Temperature electrode1T-2 ATC temperature electrode
Burette110 mL
Burette120 mL
Support rod1Length 220 mm, diameter 10 mm, M8 thread
Five-hole electrode holder1 set—
Burette sleeve1—
Teflon tube11.5 m, inner diameter 2 mm, outer diameter 3 mm
Hose protective sleeve1PVC, 1.5 m, inner diameter 3.5 mm
Quick-twist connector6 setsPEEK, presser 07B-28 thread + presser ring 030
Anti-diffusion head1—
Titration cup5100 mL
Stirring bar130 mm
Stirring bar140 mm
Reagent bottle2 setsWith bottle cap, 500 mL
Visual filter2 sets—
CO2 absorbent1 bottle500 g
Power cord1Three-pin, 1.5 m
Printing paper1 rollφ 57 mm × 30 mm
Instruction manual1—
Certificate of conformity1—
Warranty card1—

Optional electrodes (available separately):

ElectrodeMeasuring range
7102 composite fluoride electrode10⁻¹–10⁻⁶ mol/L
7101 composite sodium electrode10⁻¹–10⁻⁶ mol/L
7103 composite calcium electrode10⁻¹–10⁻⁵ mol/L
7105 composite fluoroborate electrode10⁻¹–3×10⁻⁶ mol/L
7106 composite nitrate electrode10⁻¹–10⁻⁵ mol/L
7107 composite chloride electrode10⁻¹–5×10⁻⁵ mol/L
7108 composite silver-sulfur electrode10⁻¹–3×10⁻⁷ mol/L
7110 composite iodine electrode10⁻¹–5×10⁻⁷ mol/L
7111 composite copper electrode10⁻¹–10⁻⁶ mol/L
7112 composite bromine electrode10⁻¹–10⁻⁶ mol/L
7115 composite cyanide electrode10⁻¹–8×10⁻⁶ mol/L
7116 composite ammonia gas sensing electrode10⁻¹–5×10⁻⁶ mol/L
7117 composite ammonium electrode10⁻¹–5×10⁻⁶ mol/L
7118 composite potassium electrode10⁻¹–10⁻⁵ mol/L
7119 composite carbon dioxide electrode10⁻²–10⁻⁴ mol/L
6501 glass composite electrode—

Related Models

For laboratories that prefer a reagent-based colorimetric approach, the same catalogue includes colorimetric (photometric) acid value and peroxide value analysers. These are separate models with a different measurement principle, so the choice depends on the required method and the expected sample range. Confirm the intended method before selecting a model.

Operation and Support

Which samples are supported?
Edible oils and fats, oil-containing foods, and other oil and fat products that require acid value or peroxide value monitoring.

Which standards are followed?
GB 5009.229-2025 for acid value (second method, cold-solvent automatic potentiometric titration) and GB 5009.227-2023 for peroxide value (second method, potentiometric titration).

Can other titrations be run as well?
Yes. Besides the built-in national-standard programs, a general titration mode is available, and optional electrodes extend the range of determinations.

How are results recorded?
Detection data and titration curves are stored locally with an audit trail, and results can be printed directly from the built-in thermal printer.

Product Enquiries

Contact our sales representative for product enquiries, configuration information and coordination of service requests.

Sales Contact: Grace
Email: graceliu@hmdzkj.cn
Tel / WhatsApp / WeChat: +86 17853698681


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